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中国物理学会期刊

硫化镉单晶体本征吸收边的类氢光谱系

CSTR: 32037.14.aps.12.187

THE HYDROGEN-LIKE SERIES NEAR THE CHARACTERISTIC EDGE OF THE CADMIUM SULPHIDE SINGLE CRYSTALS

CSTR: 32037.14.aps.12.187
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  • 利用CdS单晶体, 一块约厚0.1 毫米, 另一块约厚0.05 毫米, 观察它们在天然光及偏振光下的吸收光谱.在室温及液态空气温度下, 天然光的吸收指示CdS 晶体长波吸收边波长随厚度及温度而改变.在光谱仪狭缝前放一偏振片观察到长波吸收边波长随晶体C轴与偏振光电矢量简介角的改变. 在液态空气温度下观察CdS 晶体对偏振光的吸收情况, 发现在晶体本征吸收边出现由七条强而锐的谱线粗成的一个类氢光系. 测量结果发现每条谱线的波数满足下列公式: 式内k= 3 , 4 ,5, ...9 ; k= 2 的线未在光错中发现.从此式推出的CdS 晶体能级的系限加以温度较正为2.41 电子伏, 与前人用其他方法所得2.42 电子伏是很相近的. 激子的等价质量与电子质量之比为4 .3. CdS 晶体与ZnS晶体结构相似, 常数数值相近, 由此可以猜侧CdS 晶体能级的满带可能是S--离子.所观察到的激子光谱类氢系可能是S--离子的激发态.

     

    The absorption spectra of cadmium sulphide single crystals were observed with natural light and polarized light, one piece of the crystals having a thickness of about 0.1 mm and another about 0.05mm.At room and liquid air temperatures, the absorptions spectra observed with natural light indicate that the wavelength of the long wavelength limit of CdS depends upon the thickness and the temperature of the crystals.A change of the wavelength of the absorption edge which depended upon the orientation of the electric vector of the polarized light produced by a polaroid plate placed between the crystal and the slit of the spectrograph was observed. At room and liquid air temperatures, the absorption spectra of the thinner CdS crystal with polarized light were observed .The spectrum at the liquid air temperature was a hydrogen like series which consisted of seven members of strong and sharp lines located in the long wavelength side of the absorption edge of the crystal. From the results of the wavelength measurements we found that the wave number of each spectral line fulfils the following relation: where k= 3 , 4 , 5 ,...9, and the line of k=2 was not seen in the spetrum. From the above emperical formula the series limit of the hydrogen-like series of CdS crystal after the trmperature correction was found to be 2.41 eV , which is in good agreement with the value of 2.42 eV obtained by othe methods. The reduced mass of the exciton in CdS crystal was found to be about 4.3 times the mass of electron. CdS and ZnS crystals have a similar strueture, and the numerical values of their lattice constants are quite near. It could be infered that the full band of CdS crystal is pobably due to the S--ions and the observed hydrogen-like series of the excitons spectra is probably due to the excited state of S--ions.

     

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