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中国物理学会期刊

化学反应媒质中的声吸收理论及关于MgSO4水溶液的弛豫机构

CSTR: 32037.14.aps.18.501

THEORY OF SOUND ABSORPTION AND THE RELAXATION MECHANISM OF MgSO4 IN WATER SOLUTION

CSTR: 32037.14.aps.18.501
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  • 本文首先应用化学热力学方法推导出弛豫吸收公式和唯象理论的假定;其次借助于Debye-Hückel离子云理论,将所得结果应用MgSO4水溶液中去,并对以往发表的有关工作进行了讨论;最终指出,MgSO4水溶液的弛豫吸收机构用MgSO4←→Mg+++SO4--型的反应来说明是不够恰当的。

     

    The assumption of the relaxation of the reaction MgSO4←→Mg+++SO4-- to be the basis of sound absorption in water has not sufficient ground. In this paper, the author derives a formula for relaxation absorption based on the chemical thermodynamics, and the supposition from which the phenomenological theory started is also explained. With the consideration of Debye-Hückel ionic atmosphere theory, the formula obtained is applied to the water solution of MgSO4. A critical discussion is given to the existing theories.

     

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