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中国物理学会期刊

求近似波函数的一种方法

CSTR: 32037.14.aps.20.1235

A METHOD FOR OBTAINING APPROXIMATE WAVE FUNCTIONS

CSTR: 32037.14.aps.20.1235
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  • 设H为量子体系的哈密顿算符,以算符(λ-H)和(H-λ)-1作用于近似波函数ψk(0)。我们证明了,如果作用得到的函数中φk在H的变量的整个区间是连续、有限和平方可积的,则它们是比ψk(0)更接近于本征态ψk的近似波函数。由φk计算H的平均值接近于以ψk(0)为无微扰态的二级微扰的计算值。用此法计算类氢离子的极化率,得到很好的结果。

     

    An approximate wave function ψk(0) is operated on by the operators λ-H and (H-λ)-1, where H is the Hamiltonian operator of the quantum system under consideration. We have shown that, if the resulting function φk is continuous, finite and square integrable in the whole domain of the variables of H, it is a better approximate wave function to the eigenstate ψk of the system than ψk(0) is. The expecting value of H, calculated with φk as wave function approaches to that calculated by the method of second order perturbation with ψk(0) as unperturbated states. Polarizabilities of hydrogen-like ions are calculated and good results are obtained.

     

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