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中国物理学会期刊

光谱分析中“载体”作用的物理机构

CSTR: 32037.14.aps.20.360

A STUDY ON THE PHYSICAL MECHANISM OF THE "CARRIER EFFECT" IN SPECTROGRAPHIC ANALYSIS

CSTR: 32037.14.aps.20.360
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  • 实验研究了常用载体Ga2O3,Na2CO3在石墨、氧化锆、八氧化三铀、氧化钍、氧化铍及五氧化二钽等六种基体中的作用规律。实验结果指出,在上述六种基体中,载体对谱线强度的影响(logI/I0)与该元素的电离电位(V)之间有一定的比例关系。根据实验测到的电弧温度和电离度的数据,分析了载体影响的各种因素;最后我们认为,在分馏法的条件下,需要考虑电场的影响,这时,载体的作用主要是通过弧柱中的温度和电离度的

     

    The possible role of certain carrier (Ga2O3,Na2CO3) on the intensity of spectral lines in various matrices such as graphite, U3O8, ZrO2, etc., was investigated. The resultsshow that, in any matrix there is a relationship between the carrier effect (logI/I0) and the ionization potential (V) of impurity elements. From the measurements of the arc temperature and degree of ionization, we believe that in the case of carrier distillation method the electric field must be considered. The addition of these carriers brings about a change of arc temperature as well as degree of ionization in the arc column, which leads to a more suitable condition for the excitation of many elements, resulting in an increase of the intensity of spectral lines, but it has no influence on the process of evaporation.

     

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