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中国物理学会期刊

人工水晶的结晶习性与缺陷

CSTR: 32037.14.aps.28.240

THE CRYSTALLIZATION HABIT AND DEFECTS OF SYNTHETIC QUARTZ

CSTR: 32037.14.aps.28.240
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  • 本文从晶体结构入手研究了水晶的结晶习性与生长时物理、化学条件之间的关系,提出三方偏方面体单形在水晶生长过程中具有重要作用的论点。通过对水晶结晶习性的剖析,使表面结构与内部结构得到由表及里的联系。从籽晶取向(z切,y棒,x棒与z轴相交55°切型等)研究了三方偏方面体结晶习性与晶体缺陷之间的关系。结果表明:人工水晶中的缺陷主要是三方偏方面体晶面的生长痕迹,称之为“子面缺陷”;在y棒和x棒晶体中还有各族晶面之间形成的“生长锥界面缺陷”。

     

    In this article, starting with the depiction of the crystal structure, the relationship between the crystallization habit of the synthetic quartz and the physical and chemical conditions for its growth is described. The author puts forward a viewpoint that the simple form of the trigonal trapezohedron plays an important role during the growing period. By means of analysing the crystallization habit, an outer to inner relation between the external and the internal structures of the synthetic quartz has been established. Moreover, a correlation between the crystallization habit of the trigonal trapezohedron and the crystal defects has been studied for various seed orientations, namely the Z-cut, Y-cut, X-cut and the cut which intersects the Z-axis at 55°. The results of the experimental investigations show that the defects of synthetic quartz, usually called "facet defects", arise mainly from the growth traces of the crystal faces of the trigonal trapezohedron, while in the X-cut and Y-cut crystals there are still pyramidal growth interface defects formed between the various crystal faces concerned.

     

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