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中国物理学会期刊

标定X射线粉末照相指数的新图解法,推广于正交晶系与单斜晶系

CSTR: 32037.14.aps.30.369

THE EXTENSION OF THE NEW GRAPHIC METHOD FOR INDEXING DEBYE-SCHERRER PHOTOGRAPHS TO ORTHORHOMBIC AND MONOCLINIC SYSTEMS

CSTR: 32037.14.aps.30.369
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  • 本文叙述了X射线粉末照相指数的新图解法在正交晶系与单斜晶系中的应用。由于在这两个晶系中所须确定的原始参量多于2,所以不可能像在四方晶系或六角晶系的情形,一次用图解法在平面上求得晶胞的所有初基参量。本文分析了正交晶系与单斜晶系的一些特殊情形,可用新图解法对粉末照相上一些特殊情形下的衍射线指数进行标定。为方便起见,图解法是尽量用线坐标进行的。

     

    The new graphic method of indexing Debye-Scherrer photographs has been extended to orthorhombic and monoclinic crystals. Line coordinates are amply utilized. Thus the condition that the solution of a series of Diophantine simultaneous linear equations is represented by the interception of a series of conditional lines is replaced by a series of conditional points that passes through a common straight line, the reciprocal intercepts of which on the coordinate axes represent the common solution.Only special cases have been considered. For the orthorhombic system, it is supposed that among the observed lines, there exists a series of reflexions belonging to(1)(hi,0,0),(0,ki,0),(0,0,li);(2)(hi,ki,0),(0,ki,li),(hi,0,li);(3)(hi,k,l), (h,ki,l),(h,k,li) or (4)(hi,ki,l),(h,ki,li),(hi,k,li). And for the monoclinic system, it is supposed that there exists a series of reflexions belonging to (l)(hi,0,0,0),(0,ki,0),(0, 0,li);(2) (hi,ki,0), (0,ki,li); (3) (h,ki,l); (4) (hi,k,l), (h,k,li) or (5) (hi,ki, li)(hi,ki,li),(hi,ki,li),(hi,ki,li). Here the index without a subscript indicates that it remains unchanged in the family of reflexions.A novel feature in this work is that the concept of quadratic difference △isn2θij = sin2θj-sin2θi has been introduced into the graphic method. Thus if there is a set of reflexions in the monoclinic system belonging to the family (hi, k, l), and if we plot (△h2ij/△sin2θij, l△hji/△sin2θij) as conditional points, and if there exists a straight line connecting three or more conditional points arising from different △sin2θij then the reciprocal intercepts of the straight line on the coordinate axes will give A2 and 2AC cosβ, where A=λ/2a sinβ and C=λ/2c sinβ.

     

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