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中国物理学会期刊

C-15结构(Hf,Zr,Ta)V2和(Hf,Zr,Nb)V2合金超导转变的压力效应研究

CSTR: 32037.14.aps.31.1176

STUDY ON PRESSURE DEPENDENCE OF SUPERCONDUCTIVITY OF C-15 LAVES PHASE ALLOYS: (Hf, Zr, Ta)V2 AND (Hf, Zr, Nb)V2 SYSTEM

CSTR: 32037.14.aps.31.1176
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  • 本文研究了C-15结构化合物(Zr0.5Hf0.5-xTax)V2(x≤0.2)和(Hf0.5Zr0.5-xNbx)V2(x≤0.2)的超导转变温度Tc及其压力效应?Tc/?P。报道了实验方法与结果。与(Hf1-xTax)V2和(Zr1-xTax)V2的情况不同,在(Zr0.5Hf0.5-xTax)V2中Ta的引入使常压下的Tc下降,然而(?)Tc/(?)P却大为提高。因此高压下Zr0.5Hf0.45Ta0.05V2的Tc反而比Hf0.5Zr0.5V2更高。导出了一个基于角动量分波表象能带论方法的描述压力效应的新关系式。它指出导带电子波函数中的高角动量成分变化对Tc的压力效应影响比较重要。这个公式有助于理解上述复杂的实验现象,并能合理地解释某些元素(如Cs,Ba,La等)的Tc随压力剧增的事实。

     

    The superconducting transition temperatures, Tc, and their pressure dependences ?Tc/?P of some C-15 Laves phase compounds, (Zr0.5Hf0.5-xTa)V2 (x≤0.2) and (Hf0.5Zr0.5-xNbx)V2(x≤0.2) system, have been studied. A description of the experimental apparatus and results is given. Unlike the cases of (Hf1-xTax)V2 and (Zr1-xTax)V2, introduction of Ta in (Zr0.5Hf0.5-xTax)V2 depresses Tc but causes a remarkable higher ?Tc/?P. So the superconducting transition temperature Tc of Zr0.5Hf0.45Ta0.05V2 is higher than that of (Zr0.5Hf0.5)V2 at high pressure. In view of the band theory method with angular momentum representation, a new relation for the pressure dependence of elect-ron-phonon coupling (i.e. ?lnη/?lnV) is derived. It emphasized the relative importance of high angular-momentum-partials variation of the conduction band electron wave function on ?lnη/?lnV. This formulation is helpful in understanding the above-mentioned experimental results and also gives a resonable explanation to the facts that Tc of some elements, e. g. Cs, Ba and La, are substantially enhanced by pressure.

     

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