-
Y(Mn1-xCox)12属于ThMn12型四角体心结构,空间群为14/mmm,z=2。用粉末中子衍射测定了Co,Mn原子在8i,8j和8f晶位上的有序度。结构分析表明:Go优先占据8f晶位,其次占据8j晶位;在x<0.67时,几乎不进入8i晶位。最后,对实验结果作了讨论和推断。The crystal structure of the ternary compound Y(Mn1-xCox)12 With x = 0.3, 0.5 and 0.6 is body-centered tetragonal of ThMn12 type. The space group is I4/mmm, z= 2. Powder neutron diffraction studies on this system has been performed to determine the possible ordering of the Co and Mn atoms on 3 nonequivalent crystallo-graphic sites 8i, 8j and 8f. The structure analyses at room temperature shows that the Co atoms tend to occupy the 8f sites primarily and then the 8j sites. They avoid the 8i sites when x is lower than 0.67. The experimental result is discussed and an inference is drawn.







下载: