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中国物理学会期刊

BeAl2O4:Cr3+的晶场能级

CSTR: 32037.14.aps.32.64

CRYSTAL-FIELD ENERGY LEVELS OF BeAl2O4:Cr3+

CSTR: 32037.14.aps.32.64
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  • 金绿宝石中镜对称格位上Cr3+(Ⅱ)离子的4T2,4T1和2E能级与该材料的激光运转有关。4T2和4T1能级各分裂成三个子能级。为从偏振吸收谱上确定BeAl2O4:Cr3+的能级图,本文计算了4T2和4T1的分裂,找到了对谱方法,得到了表征能级分裂的参量K1和K2的值。最后给出了以低点群不可约表示标号的、BeAl2O4:Cr3+(Ⅱ)的晶场能级图。

     

    The 4T2,4T1, and 2E levels of Cr3+ ion on the mirror-site in an alexandrite crystal are in relation to the laser operation of that material. The 4T2 (or 4T1) level splits into three sublevels. In order to determine the energy levele diagram of Cr3+ ions in chrysoberyl, the splitting of the 4T2 and 4T1 are calculated. We have discussed the anisotropic transition intensities of corresponding absorption bands and have found a method to fit the spectra. Furthermore, the values of the parameters K1 and K2 that represent the magnitude of the splitting are obtained, and the crystal field energy level diagram of BeAl2O4:Cr3+(II), labelled by the irreducal representations of point group C3, is given.

     

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