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中国物理学会期刊

(Fe0.1Co0.55Ni0.3578Si8B14金属玻璃的晶化过程及压力的影响(Ⅱ)——晶化温度和晶化激活能

CSTR: 32037.14.aps.34.1327

THE CRYSTALLIZATION PROCESS OF METGLASS (Fe0.1Co0.55Ni0.35)78Si8B14 AND THE EFFECT OF HIGH PRESSURE (Ⅱ)——The Crystallization Temperature and The Crystallization Activation Energy

CSTR: 32037.14.aps.34.1327
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  • 本文用高压下原位电阻测量法研究了3GPa以下(Fe0.1Co0.55Ni0.35)78Si8B14金属玻璃的晶化温度Tx,并用Kissinger法求得不同压力下金属玻璃的晶化激活能△Ex。测量结果表明,施加压力时这种合金的Tx并不是单调地、更不是线性地升高的,而是在上升的总趋势中还存在某些局部的转折。这和一些被广泛引用的结论是不同的。晶化激活能△Ex也随压力作类似趋势的变化。分析认为,压力促进晶化时的成核过程,而抑制晶核的扩散性长大。两者的综合作用是造成△Ex、从而也构成Tx非单调变化的原因。压力除了通过△Ex影响Tx以外,指数前因子的压力效应也可以使晶化温度产生重要的改变。

     

    In this paper, the pressure dependence of the crystallization temperature Tx and the crystallization activation energy △EX of metglass (Fe0.1Co0.55Ni0.35)78Si8B14 werestudied by measuring the electrical resistivity in-situ under pressure up to 3 GPas. It was found that application of high pressure not linearly, even not monotonicaly riases the Tx, as usually described in literatures for pressure dependence of Tx in metglasses, but shows some local detours on Tx vs. P curve in a general rising tendency. △Ex shows same behaviour analogous to that of Tx as the pressure rises. An analytical discussion indicates that pressure promotes the nucleation process and restrains the diffusional growing up of the crystallized nuclei on heating the metglass. As a combined result of the mutual contrary effects of pressure on nucleation activation energy a,nd diffusion activation energy, it gives rise the above non-monotonic rising behaviour of △Ex and Tx of the metglass studied. In addition to △Ex, pressure may also markedly affect the preexponential factor and produces a considerable change on crystallization temperature.

     

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