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中国物理学会期刊

Sm2(TM)17合金的磁性(自旋再取向相变)研究

CSTR: 32037.14.aps.34.1385

STUDY OF MAGNETIC PROPERTIES (SPIN REORIENTATION PHASE TRANSITIONS) IN Sm2(TM)17 ALLOYS

CSTR: 32037.14.aps.34.1385
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  • 本文研究了Sm2(FeNiCoM)17合金(M为非磁性组元)的磁性。样品由六角结构无序型的2∶17主相及少量FeNi合金杂相组成。在六角结构的e轴方向(易磁化方向)观察到下述异常现象:低温(273K以下)时的磁化及反磁化曲线发生明显的跃变,跃变时相应的磁场Hr随温度下降而增大;磁滞迴线是蜂腰型的,温度愈低蜂腰愈明显;升温时磁化强度随温度变化(1.5K至居里点TC)的曲线上出现极大值,其相应的温度Tt随磁场增大而降低;降温时观察到了热磁滞后现象。但在基面(难磁化方向)上及Co含量增多(>18at%)时,样品却表现了正常的铁磁行为。本文提出用磁矩非共线结构排列的自旋再取向相变来解释上述异常现象,并给出自旋倒向所需越过的能垒高度U=9.2×10-15erg,用设想磁结构的模型得到的磁化强度的计算值与实验值也符合得较好。

     

    The magnetic properties of pseudobinary Sm2(FeNiCoM)17 alloys in which M are nonmagnetic elements have been studied. The sample consists of disordered hexagonal 2:17 phase (TbCu7-structure) coexisting with FeNi. Anomalous magnetic properties along the c-axis (easy magnetization direction) have been observed. Below the room temperature, the magnetization and reverse magnetization curves exhibit obvious jumps. The magnetic fields corresponding to the jumps Hr increase with the temperature decreasing. The hysteresis loops show wasp-waisted character. The curve of magnetization vs. temperature has a maximum, the corresponding transition temperature Tt decreases with the magnetic field increasing. During cooling, the thermal magnetic hysteresis phenomena have been found at some values of magnetic field. On the basal plane (hard magnetization direction) and at higher Co concentrations (>18at%), the alloys show normal ferromagnetic behaviors. Most of the phenomena observed can be explained in terms of spin reorientation phase transition leading to non-collinear spin arrangements. The reversal of spin direction must cross over an evergy barrier, the height of which is U = 9.2×10-15 erg. The calculated values of magnetization are in good agreement with the observed ones.

     

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