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中国物理学会期刊

金属中f电子局域磁矩及其退局域化的一个模型(Ⅰ)

CSTR: 32037.14.aps.34.1442

A MODEL FOR LOCAL MAGNETIC MOMENT AND ITS DELOCALIZATION OF f ELECTRONS IN METALS (Ⅰ)

CSTR: 32037.14.aps.34.1442
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  • 本文提出了一个模型,其中f电子束缚在费密面附近的一个窄带内,s-p-d电子是自由的,还考虑了它们之间的杂化。数值计算的结果表明f电子在退局域化过程中有一定的稳定性,温度和杂化对之有明显的影响。文中给出了不同参数空间的相图。最后对稀土变价现象进行了定性讨论。

     

    In this paper we suggest a model in which f electrons are bound in a narrow band near Fermi level, s-p-d electrons are regarded as free, and hybridization between them is considered. Numerical results show that certain stability of f electrons exists under delocalization and is dramatically influenced by temperature and hybridization. Phase diagrams in different parameter spaces are plotted. Finally the case of intermediate valence in RE is discussed qualitatively.

     

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