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本文用电容法测量了PTS单晶从77—273K平行于分子链方向和垂直于分子链方向的热膨胀系数,实验观察到沿链方向的热膨胀系数在195K附近有突变,在200K附近出现负值。对此,我们作了定性的讨论。The thermal expansion coefficients (along and normal to the chain direction) of PTS have been measured by differential parallel-plate capacitances from 77 K to 273 K. A sudden change near the phase transition temperature 195 K and a negative expansion coefficient near 200 K along the chain direction have been observed. The causes of these result are discussed qualitati-vly.







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