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中国物理学会期刊

金属离子对银溶胶的聚集作用及形成的分数维结构

CSTR: 32037.14.aps.36.1289

THE AGGREGATION EFFECT OF METAL IONS ON SILVER SOL AND THE FRACTAL STRUCTURE FORMED

CSTR: 32037.14.aps.36.1289
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  • 本文研究了一些离子作用于银溶胶而引起聚集的情况。一价金属离子对银溶胶的聚集作用不明显,第Ⅱ主族的金属离子能够引起银溶胶的聚集而形成分形体(Fractal)态,且随着金属离子半径的增大,其聚集能力增强,对于三价金属离子Al3+,它也能引起银溶胶的聚集而形成分形体态。酸根阴离子一般不直接引起银溶胶的聚集,但能影响银溶胶的聚集。

     

    We have studied the aggregation of silver sol by mixing silver sol with several kinds of ions. We found that it is very difficult for the monovalent metal ions to make silver sol aggregate. The metal ions of the second main group can make silver sol aggregate and form fractal state. With the radii of metal ions increase, their ability of aggregation increases accordingly. The metal ion of the third main group A13+ can also make silver sol aggregate and form fractal state. As for acid radical ions, they can not make silver sol aggregate directly, but they can influence the speed of the aggregation and final state of silver sol. The simple explanations of these phenomena were given. We also found that the speed of aggregation and final state of silver sol were determinded by the state of silver sol and the proportion of metal ions in silver sol.

     

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