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中国物理学会期刊

能量分辨率对EXAFS的影响

CSTR: 32037.14.aps.36.1496

INFLUENCE OF ENERGY RESOLUTION ON EXAFS

CSTR: 32037.14.aps.36.1496
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  • 测量EXAFS谱时,系统的能量分辨率是影响其结果的重要因素。本文提出了分辨率影响结构参数的计算方法,以Ge,Ni样品为例,测量及计算了不同分辨率下的结构参数的差异。测量结果与计算结果符合得很好,讨论了分辨率如何影响EXAFS谱及结构参数,给出了修正方法。

     

    The finite energy resolution of EXAFS spectrometer is an important effect on EXAFS measurement. It lowers the EXAFS amplitude and the decrement in smaller k is greater than that in larger k. That causes smaller coordination number and the relative mean square displacement obtained from EXAFS data. This paper proposes a method to calculate the effect of the resolution on the structural parameters extracted from EXAFS. Structural parameters of Ge and Ni, as examples, were measured and calculated with different resolutions and the results are consistent with each other. The manner of how the effect occurs is discussed and a method to correct the influence of the finite energy resolution is presented.

     

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