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中国物理学会期刊

研究价涨落化合物的一种新方法

CSTR: 32037.14.aps.36.892

A NEW APPROACH TO INVESTIGATING THE VALENCE FLUCTUATION COMPOUNDS

CSTR: 32037.14.aps.36.892
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  • 本文讨论两种典型的价涨落化合物——SmB6和SmS——的基态性质。由于Sm离子上的定域的直接d-f杂化被反演对称性禁戒,本文采用声子中介的定域的非直接d-f杂化模型。采用正则变换方法处理声子中介的d-f杂化项,得到一个“小极化子”类型的有效哈密顿量。应用自洽场近似处理这个有效哈密顿量,得出基态时的非零能隙和f能级的非整数占有数。这些结果可用以解释在SmB6和SmS中观察到的小能隙和价涨落现象。

     

    The ground state properties of the Sm-based valence fluctuation compounds are discussed by introducing an indirect on-site hybridization mediated by phonons, as the direct on-site hybridization is forbidden by inversion symmetry. The Hamihonian including this indirect hybridization is transformed into an effective Hamihonian of a "small polaron" type by means of a. canonical transformation. A self-consistent field approximation is used, a non-zero energy gap and the noninteger occupation of the f level have been given. The results obtained can be used to explain the small energy gap and the valence fluctuation phenomena observed in SmB6 and SmS.

     

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