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中国物理学会期刊

SrCl2:Co++EPR谱电场效应的理论解释

CSTR: 32037.14.aps.37.136

A THEORETIC EXPLANATION OF ELECTRIC HELD EFFECT OF EPR SPECTRA OF SrCl2:Co++

CSTR: 32037.14.aps.37.136
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  • 本文从理论上研究了111方向电场对SrCl2:Co++的EPR谱的影响。结果表明:外电场使晶格发生畸变而偏离原来的Oh对称,成为C3v。由此圆满地从理论上解释了零场分裂因子D随电场强度E线性变化的实验规律,并从理论上预言了晶格在平行电场方向的变化率为α=—8×10-5α0mm/kV,在垂直电场方向的变化率β=1.66×10-4α0 

    The effect of electric field applied along 111 on EPR spectra of SrCl2:Co++ has been investigated. The result shows that electric field causes the crystal lattice to distort and deviate from its original cubic Oh symmetry to C3v symmetry. We have successfully explained the experimental rule that zero field splitting parameter D depends linearly upon electric field strength E and also predicted the coefficients of the change of the structure parameters a = - 8×10-5 a0 mm/kV (parallel to the electric field), β= 1.66×10-4 a0 mm/kV (perpendicular to the electric field).

     

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