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本文将Wilets等人提出并由作者加以改进的二体电子关联变分方法推广到多电子原子一般激发态结构的计算。对He原子及其等电子系列(1s)(nl)电子组态的激发单重态n1L、三重态n3L,Be原子及其等电子系列(1s)2(2s)(nl)3L和B原子(1s)2(2s)2(nl)2L等激发态进行了计算,结果表明:这种方法的波函数结构简单,便于应用,不仅计算量小,The variational approach to two-body correlations in atoms proposed by Wilets et al, and developed by bresent authors is applied to treat the correlations of excited states of the atoms. The (ls)(nl)1,3L excited states of helium iseelectronic sequence, the (1s)2(2s)(nl)3L states of beryllium isoelectronic sequence and the (1s)2(2s)2(nl)2L states of boron have been calculated.The results show that these correlation wave functions have simple structure and are feasible in caloulation application. The accuracy of our method is very close to those of more complicated CI and 1/Z perturbation expansion methods.







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