The electronic structure of Nd2CuO4 has been calculated self-consistently by WLAPW method. Because of the interactions (hybridization) between the electrons in the localized Nd 4f bands and those in the conduction band, a≈4 states/eV. cell DOS peak of the Cu-0(1) dp a band is presented at 0.18 eV above the Fermi energy, which may be used as a possible interpretation of the superconducting transition in Nd2-xCexCuO4 with x.