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中国物理学会期刊

A(B0.51B0.52)O3系统中三种有序态的稳定性初探

CSTR: 32037.14.aps.40.498

STABILITY OF THREE KINDS OF ORDERED STRUCTURES IN A (B0.51B0.52)O3 FERROELECTRICS

CSTR: 32037.14.aps.40.498
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  • 在A(BB0.51B0.52)O3钙钛矿型铁电陶瓷材料中,除了在较高温度下都能有稳定的型超格子有序结构外,在室温和-150℃情况下,还分别观察到1/2和1/2型超格子有序结构,本文引入长程相互作用,并利用8点集团变分模型,在不同温度范围内分析了前面三种有序态的稳定性,所得结论与实验结果一致。

     

    In A(BB0.51B0.52)O3 perovskite-like ferroelectrics. besides the stable 1/2〈lll〉-typeordered structure, two new kinds oi ordered structures, 1/2〈110〉 and 1/2〈100〉 superlattices, have been observed at room temperature and -150℃ respectively. In this paper, the longrange interactions are introduced into the eight-point cluster variation method to analyse the stabilities of the three kinds of ordered structures. The results are in good agreement with experimental observations.

     

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