Laser-induced fluorescence excitaion spectrum of gas-phase dichlocarbene (CC12) cooled in the supersonic jet has been observed in the range of 497-517 nm. The K-structrue of the (v1,v2,0)-(0,0,0) vibrational bands was resolved. About 80 su-bbands were assigned. v＇1= 643.5cm-1, v＇2 = 308.0cm-1 and the anharmonic costants, and (A＇-B＇) = 3.67cm-1, (A" - B") = 1.80cm-1 were obtained from the analysis of spectra.