搜索

x
中国物理学会期刊

梳型高分子聚合物向列相液晶的相变

CSTR: 32037.14.aps.41.609

PHASE TRANSITION OF COMB POLYMER NEMATIC LIQUID CRYSTAL

CSTR: 32037.14.aps.41.609
PDF
导出引用
  • 本文根据Freiser关于向列相液晶分子相互作用模型,利用平均场理论,建立了梳型高分子聚合物向列相液晶分子的哈密顿量,导出序参数自洽方程,得到各向同性相至单轴向列相以及单轴至双轴向列相的相变,结果表明,当分子主、侧链耦合项中排斥作用及主、侧链中较强向列相场的场强增大时,单轴至双轴向列相相变温度升高,并从一级相变逐渐变为二级相变。

     

    The Hamiltonian of comb polymer nematic liquid crystal molecule is constructed by using the interaction model of nematic liquid crystal molecule proposed by Freiser and the mean field theory. The self-consistancy equations of order parameters are derived and the phase transitions from isotropics to uniaxial nematics, uniaxial to biaxial nematics are obtained. The results show that when the repulsion in coupling term of backbone and side chain getting greater, the nematic field of the stronger one between those of backbone and side chain getting stronger, the uniaxial-biaxial phase transition temperature will rise and the phase transition will gradually change from first order to second order phase transition.

     

    目录

    /

    返回文章
    返回