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中国物理学会期刊

染料J聚集体Langmuir-Blodgett膜光致发光谱的温度影响与多声子跃迁

CSTR: 32037.14.aps.42.1095

MULTIPHONON TRANSITION AND TEMPERATURE DEPEN-DENCE OF PHOTOLUMINESCENCE SPECTRA OF DYE J-AGGREGATE LANGMIUR-BLODGETT FILMS

CSTR: 32037.14.aps.42.1095
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  • 在20—300K的范围内测量了三种花青染料聚集体Langmiur-Blodgett(LB)膜的光致发光谱。随着温度下降零声子线J峰强度的增大,观察到声子伴带的异常加强。分析表明生长不均匀的聚集体B膜具有低维晶体的特性,声子耦合强,且无辐射跃迁起着重要的作用。

     

    In temperature range of 20K to 300K, we measuded photoluminescence spectra of heterogeneous J-aggregate Langmiur-Blodgett (LB) films made of three kinds of cyanine dye. With temperature reduced, while the intensity of J-peak, the zero phonon line increased, anomalous enhancement of the phonon sideband was observed. Analysis shows that J-aggregatc LB films are of characteristics like that of low dimensional crystal, they have strong phonon coupling, and nonradiative transition plays important role.

     

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