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中国物理学会期刊

碘掺杂聚乙炔电子自旋共振及导电性的研究

CSTR: 32037.14.aps.42.340

STUDIES ON ELECTRIC CONDUCTIVITY AND ELECTRON SPIN RESONANCE FOR IODINE DOPED POLYACETYLENE

CSTR: 32037.14.aps.42.340
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  • 用四探针法测量掺碘聚乙炔薄膜CH(I3)yx,当y=1.0%,4.2%和8.3%时面电阻随温度的变化,发现它们可用变程跳跃(VRH)模型很好的描述。用电子自旋共振(ESR)谱仪研究了不同温度下低浓度碘掺杂聚乙炔的自旋磁化率、峰峰宽等。并给出相应的理论解释。

     

    The four-probe technique is used to measire the electric conductivity of polyacetylene doped with iodine. For dopant concentration ranging from 1.0 to 8.3 mol% in cis-(CH)x, the obtained conductivity values for different temperatures are consistent with the variable-range hopping model. The mechanisms of the temperature dependence of the ESR spin magnetic susceptibility and line width for low iodine concentrations are studied.

     

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