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中国物理学会期刊

向列型液晶中分子短程关联的研究

CSTR: 32037.14.aps.43.1241

A STUDY OF MOLECULAR SHORT RANGE CORRELATIONS IN NEMATIC LIQUID CRYSTALS

CSTR: 32037.14.aps.43.1241
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  • 向列型液晶中的分子短程关联有重要物理效应。但取向两体势包含高阶项时,现行理论不能给出可靠计算。本文在格胞理论的基础上发展新的数值方法解平衡态方程。我们不对取向分布函数作任何经验展开而得到精确的分子取向分布。给出了向列相一各向同性相转变点的序参数、熵变等量的准确数值结果,从而得到短程关联对推广的平均场理论的修正。

     

    Some important physical effects appear due to molecular short range correlations in nematic liquid crystals. When the orientational pair potential including the higher order terms, recent theories are not yet able to give reliable calculations. This paper is devoted to developing a new numerical method to solve the equation for equili-brium state, based upon the cell theory. We do not use any empirical expansions for the orientational distribution function but obtain the accurate molecular orientational distrbutions. Then we give the accurate numerical results of the order parameter at the phase transition, the entropy change etc., and obtain the correction for the Sene-ralized mean field theory made by the short range correlations.

     

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