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中国物理学会期刊

14N核四极共振的偏共振效应

CSTR: 32037.14.aps.43.1371

OFFSET EFFECTS OF 14N NUCLEAR QUADRUPOLAR RESONANCE

CSTR: 32037.14.aps.43.1371
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  • 用虚拟1/2自旋算符讨论了核四极共振(NQR)中自旋I=1的自旋系统对激发脉冲宽度和频率偏置的响应。用单脉冲和双脉冲来观测的核四极共振信号与理论预期相符合。此外还证明,若只考虑射频场在分子电场梯度(EPG)张量主轴坐标系(PAS)中的一个轴上的分量(即有效射频场分量)的作用,就可用NMR矢量模型来处理I=1的核自旋系统。

     

    The NQR responses of the nuclear spin system with I=1 to frequency offsets and pulse widths are examined with fictitious 1/2-spin operator formalism. The transverse magnetization and longitudinal magnetization are observed with one pulse and two pulses sequence, respectively. The experimental results measured with NQR probe are consistant with theoretical calculations. It is shown that the NMR vector model can be applied to the NQR system for I=1 when the rf excitation is intro-duced on one axis in EFG principal axis frame.

     

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