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中国物理学会期刊

空间限制与应变对发光多孔硅喇曼光谱的影响

CSTR: 32037.14.aps.43.494

EFFECT OF PHONON CONFINEMENT AND STRAIN ON RAMAN SPECTRA FROM LIGHT-EMITTING POROUS SILICON

CSTR: 32037.14.aps.43.494
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  • 发光多孔硅的喇曼光谱在520cm-1附近呈现一锐峰,峰位的红移随多孔度的增大而增大采用微晶模型拟合喇曼谱的线形,发现除了光学声子的空间限制效应,硅单晶的应变对峰位的移动也有显著贡献。通过谱形的拟合估算了硅微粒的应变,与已报道的X射线衍射结果相一致。在多孔硅的喇曼光诸中没有观察到起源于非晶硅的光散射信号。

     

    The typical Raman spectrum from light-emitting porous silicon shows a sharp peak near 520cm-1. The peak wavenumber decreases with the increase of porosity. The lineshape analysis shows that both phonon confinment and strain effects in nanocrystal silicon must be taken into account for the measured Raman spectra. The strain in porous silicon film is estimated and the result is consistent with that given by X-ray diffraction studies. No light scattering from amorphous phase is observed.

     

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