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中国物理学会期刊

链间耦合对反式聚乙炔中孤子能谱及其局域振动模的影响

CSTR: 32037.14.aps.43.516

EFFECTS OF INTERCHAIN COUPLING ON THE ENERGY SPECTRA AND THE LOCALIZED MODES OF SOLITON 1N POLYACETYLENE

CSTR: 32037.14.aps.43.516
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  • 从计及了链间相互作用项的SSH模型出发,讨论了相邻两条链间电子跃迁对反式聚乙炔中孤子能谱及孤子附近的局域振动模的影响,结果发现:(1)孤子能级偏离了禁带中心,能谱的对称性被破坏。(2)局域振动模发生劈裂,劈裂后两模的振动位形具有与原模相同的结构,但它们的频率和最大振幅均不同于原局域模。另外,模的频率还与两条链上的孤子类型以及链的相对序列有关。

     

    The effects of interchain coupling on the energy spectra and the localized modes around soliton have been studied based on a generalized SSH model including the interehain electronic transfer term. Duo to the interchain coupling, the soliton level shifts from the center of forbidden gap, and the symmetry of energy spectra is destroyed. The localized modes obtained from SSH model are splitted and their frequencies are changed. Besides, the change of freqencies is also related to the different relative ordering of the two neighboring chains, and different solitons in the two chains.

     

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