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中国物理学会期刊

费密共振和甲烷的振动能谱

CSTR: 32037.14.aps.46.1073

FERMI RESONANCES AND VIBRATIONAL SPECTRUM FOR METHANE

CSTR: 32037.14.aps.46.1073
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  • 用局域模模型来解释甲烷的伸展和弯曲振动能谱,其中伸展振动和弯曲振动间的相互作用用费密共振项来描写,它由一个伸展振子的玻色产生(或湮没)算子和两个弯曲振子的玻色湮没(或产生)算子乘积的Td不变组合构成.这模型包含10个参数,与已发表的甲烷振动能谱的实验数据比较,得到能量的方均根偏差为12.38cm-1.

     

    The boson realization model with Fermi resonances is used for explaining both stretching and bending vibrational spectra in methane. The interactions between stretching and bending vibrations are described by Td symmetric Fermi resonance terms that couple one creation (or annihilation) operator of stretching vibrations with two annihilation (or creation) operators of bending ones. This model provides a ten-parameter fit to the published experimental vibrational- eigenvalues of methane with the root-mean-square energy deviation 12.38cm-1.

     

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