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运用量子亏损理论,并与参考系变换及本征通道R-矩阵法相结合,建立了描述氢分子里德伯态的预解离过程的理论方法.通过对氢分子的3pπD1πu+和4pσ B″1Σu+电子态的预解离过程的研究,阐明其解离的机理,并给出预解离的线宽.The predissociation of H 2 in its Rydberg states has been studied using the multichannel quantum defect theory,combined with the frame transformation and the non iterative eigenchannel R matrix method.The predissociation line positions and the widths are calculated for 3pπ 1πu+(v=3,J=1,2) and 4pσ B″1Σu+(v=2,J=1,2) levels.The predissociation mechanisms are discussed.







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