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中国物理学会期刊

PLZST反铁电陶瓷电场诱导相变与相稳定性的研究

CSTR: 32037.14.aps.47.1727

INVESTIGATION OF ELECTRIC FIELD-INDUCED ANTIFERROELECTRIC TO FERROELECTRIC PHASE TRANSITION AND PHASE STABILITY OF PLZST CERAMICS

CSTR: 32037.14.aps.47.1727
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  • 在三方铁电(FE)-四方反铁(AFE)的准同型相界附近制备了一系列组份为(Pb0.97La0.02)(Zr1-x-ySnyTix)O3(x=0.09或0.1;0.16≤y≤0.38)的反铁电陶瓷.研究了Sn含量y对电场诱导AFE→FE相变电场Ec、反铁电双电滞回线损耗ΔE、以及温度诱导FE→AFE相变温度TFE,AFE→顺电(PE)相变温度Tc的影响.沿AFE-FE相界Ti含量一定的条件下,Ec随着Sn含量y的增加而增大,ΔE减小,TFE与Tc均降低.场诱相变的回线参量Ec,ΔE与相变温度TFE和Tc相关联.在直流偏压下用原位X-射线衍射表征了相变时晶格结构的变化,结果表明,当电场达到AFE→FE相变临界场时,伴随相变的发生,晶格结构由四方相转变为三方相,晶胞体积增大.

     

    We have prepared antiferroelectric ceramics with compositions of (Pb0.97La0.02)(Zr1-x-ySnyTix)O3(x=0.09 or 0.1; 0.16≤y≤0.38) near antiferroelectric (AFE)tetragonal-ferroelectric (FE)rhombohedral morphotropic phase boundary. The effects of Sn content on electric field-induced AFE→FE switching field Ec, double-hysteresis-loop width ΔE, and temperature-induced FE→AFE phase transition temperature TFE, AFE→paraelectric (PE) transition temperature Tc are investigated. At constant Ti content x, both TEF and Tc decrease with increase of Sn content y. Electric hysteresis loop measurement demonstrates an increase of Ec and decrease of ΔE when Sn content y increases. Furthermore, we also find that Ec and ΔE are related with TFE and Tc. In situ X-ray diffraction under dc bias field shows that symmetry changes from tetragonal phase to rhombohedral phase with an increase of c axis,and an increase of lattice volume.

     

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