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中国物理学会期刊

SF2自由基3d,5s里德伯态的实验确认

CSTR: 32037.14.aps.47.1776

DETERMINATION OF 3d AND 5s RYDBERG STATES OF SF2 RADICAL

CSTR: 32037.14.aps.47.1776
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  • 利用自行研制的脉冲直流放电装置产生SF2自由基,结合共振增强多光子电离(REMPI)技术,研究了27—294nm范围内SF2自由基(2+1)REMPI激发谱,获得了SF2自由基3d,5s里德伯态相应的带源及被激活的对称伸缩振动模的振动频率,并估算了这些态的量子亏损值.

     

    A pulsed dc discharge in a pulsed supersonic beam has been developed as an efficient source of producing free radicals. Spectra of the SF2 radical were observed between 272 and 294 nm by (2+1) resonance-enhanced multiphoton ionizition (REMPI) spectroscopy. Vibrational progressions associat-ed with 3d and 5s Rydberg states were assigned. The spectroscopic values ω'1 (a1, symmetric stretch-ing), band origin T0 and quantum defect δ of these Rydberg states were reported.

     

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