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中国物理学会期刊

利用三阶微商吸收光谱确定C60分子能隙

CSTR: 32037.14.aps.47.208

DETERMINATION OF THE ENERGY GAP OF C60 MOLECULE USING THIRD-ORDER DERIVATIVE ABSORPTION SPECTROSCOPY

CSTR: 32037.14.aps.47.208
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  • 利用三阶微商吸收光谱观测到可见区C60分子电子光谱中丰富的振动光谱结构.通过对此类电子-振动跃迁的指认分析,给出了C60分子部分振动模频率,确定了C60分子能隙.

     

    More detailed absorption transitions of C60 in the visible region are observed from the third-order derivative absorption spectra.The spectra are fitted with Lorentzian line shapes,and the transition energies are determined.The assignment of the transitions in visible region is discussed,some vibronic modes are given,and finally the energy gap of C60 molecule is determined.

     

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