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中国物理学会期刊

ErFe11-xCoxTi化合物的结构与磁性研究

CSTR: 32037.14.aps.47.990

STRUCTURAL AND MAGNETIC PROPERTIES OF ErFe11-xCoxTi COMPOUNDS

CSTR: 32037.14.aps.47.990
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  • 粉末样品的X射线衍射和热磁曲线测量表明,所有的ErFe11-xCoxTi(x=0—11)化合物都结晶ThMn12型结构,且具有良好的单相性.Co替代Fe导致居里温度的显著提高和晶格常数的单调减小,4.2K下的饱和磁化强度Ms随Co含量的增加在x=3处呈现极大值.ErFe11-xCoxTi化合物当x≤4时,在室温下具有单轴磁晶各向异性,当6≤x≤9时,样品的易磁化方向垂直于c轴

     

    X-ray diffraction patterns and thermomagnetic curves show that all compounds are almost of single phase.All ErFe11-xCoxTi compounds (x=0—11) crystallize in the ThMn12-type structure.Substitution of Co for Fe leads to an increase of Curie temperature and a monotonic decrease of lattice constants.The composition dependence of saturation moments exhibits a maximum at about x=3. The easy magnetization direction (EMD) at room temperature,for x≤4, is along the c-axis, for 6≤x≤9,is perpedicular to the c-axis, while for further increasing x, it goes back to the c-axis. The interesting change of EMD of ErFe11-xCoxTi compounds may result from the preferential occupation of Co and the different contribution to the magnetocrystalline anisotropy from different transition-metal sites.For all ErFe11-xCoxTi compounds, a spin reorientation occurs below the Curie temperature.A tentative phase diagram for ErFe11-xCoxTi compounds has been given.

     

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