搜索

x
中国物理学会期刊

聚噻吩中双电子极化子附近的二维局域振动模

CSTR: 32037.14.aps.48.1938

TWO-DIMENSIONAL LOCALIZED VIBRATIONAL MODES OF POLYTHIOPHENE AROUND AN ELECTRONIC BIPOLARON

CSTR: 32037.14.aps.48.1938
PDF
导出引用
  • 将聚噻吩的一维SSH孤子模型推广到二维平面,研究了聚噻吩双电子极化子附近的二维局域振动模.计算结果表明双电子极化子附近存在15个局域振动模,其中4个奇宇称模与4条强红外吸收谱线1020,1120,1200,1323cm-1相对应,4个偶宇称模恰与4条Raman吸收峰700,1047,1175,1220cm-1一致.

     

    In consideration of the influence of a planar polythiophene configuration,we study the localized vibrational modes around an electronics bipolaron by using a two-dimensional SSH model.Fifteen lo-calized vibrational modes have been found,among them,four infrared active localized vibrational modes and four Raman active ones could be used to interpret the four observed intense infrared ab-sorption lines at 1020,1120,1200 and 1323 cm-1,and the four Raman active absorption peaks at 700,1047,1175 and 1220 cm-1,respectively.

     

    目录

    /

    返回文章
    返回