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中国物理学会期刊

基态简并和非简并高分子的光吸收和量子晶格涨落

CSTR: 32037.14.aps.48.2308

SUBGAP ABSORPTION AND QUANTUM LATTICE FLUCTUATION IN DEGENERATE AND NONDEGENERATE POLYMERS

CSTR: 32037.14.aps.48.2308
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  • 通过一个简单的孤子反孤子对模型来模拟一维有机高分子中的量子晶格涨落,高分子中电子能隙内的光吸收是由孤子反孤子对激发的两个分别来源于导带的最低未占据和价带的最高占据离散能级之间的跃迁所产生的.这样的光吸收没有能隙.结果明显表明,基态非简并将抑制量子晶格涨落,从而减少电子能隙内的光吸收,使得基态非简并高分子的光吸收有一相对明显的吸收边,这与实验是一致的.

     

    By using a simple model of soliton-antisoliton pairs to simulate the quantum lattice fluctuations in one-dimensional organic polymers, in which the subgap absorption results from the transitions between the lowest unoccupied and the highest occupied levels off the conduction and valence bands, respectively, in the soliton-antisoliton excitations. There is no gap in the absorption. Our result indicates clearly that the nondegeneracy of ground-states suppresses the quantum fluctuations, so that the subgap absorption is reduced and there is a related clear onset in the absorption spectrum of nondegenerate polymers, which is in agreement with experiments.

     

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