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中国物理学会期刊

Pb(Zr,Sn,Ti)O3反铁电陶瓷的低温相变扩散与极化弛豫

CSTR: 32037.14.aps.49.2300

INVESTIGATION OF DIFFUSED PHASE TRANSITION AND POLAR RELAXATION IN Pb(Zr,Sn,Ti)O3 ANTIFERROELECTRIC CERAMICS

CSTR: 32037.14.aps.49.2300
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  • 用弱场介电温谱、热释电流谱、强场电滞回线和变温X射线衍射谱研究了微量La掺杂Pb(Zr,Sn,Ti)O3(PZST)反铁电(AFEt)陶瓷在-100—180℃温区内的结构与电学特性.弱场介电温谱显示,AFEt陶瓷在低温段(-100—50℃)呈现介电频率弥散(0.1—100kHz)和扩散型相变的特征,而变温X射线衍射谱却表明材料在这一温区内保持四方相结构;低温下经强场作用后,AFEt被诱导为亚稳三方铁电态,介电频率弥散消失.基于多元复杂化合物的组分起伏理论,讨论了PZST AFEt陶瓷

     

    Microstructure and electrical properties of lanthanum-modified Pb(Zr,Sn,Ti)O3(PZST) antiferroelectric (AFE) ceramics have been investigated by weak field dielectric, pyroelectric response, strong field polarization, and X-ray diffraction (XRD) techniques at different temperatures. Diffused phase transition and dielectric frequency dispersion (0.1—100kHz) have been observed within the temperature range of -100—50℃. However, XRD indicates that AFE ceramics are of tetragonal phase within the above-mentioned temperature range. Under a strong electric field, AFEt will be switched to a metastable ferroelectric (MFE) state, accompanying with the disappearance of dielectric frequency dispersion. Then the MFE state changes to AFE state again as temperature increases, producing a strong pyroelectric current peak. A new model considering compositional fluctuation on a nanometer scale in PZST antiferroelectric ceramics has been suggested to explain the polar relaxation in AFE state.

     

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