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中国物理学会期刊

用能量自洽法研究碱金属双原子分子的势能曲线

CSTR: 32037.14.aps.49.2352

STUDY ON THE POTENTIAL ENERGY CURVES OF ALKALI DIATOMIC MOLECULES WITH ENERGY CO NSISTENT METHOD

CSTR: 32037.14.aps.49.2352
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  • 用能量自洽法(ECM)研究了碱金属双原子分子一些电子激发态的势能曲线:Na2 分子的21Πg,43Πg和b3Πu电子激发态,K2分子的a3Σ+u,21Πg,B1Πu和A 

    The studies on the potential energy curves of the electronic excited states 21Πg, 43Πg, b3Πu of Na2, the states a3Σ+u, 21 Πg, B1Πu, A1Σ+u of K2 and the state 11Πg of Cs 2 molecules by using the energy consistent method (ECM) are reported here . The results show that the present ECM potentials agree very well with the know n Rydberg-Klein-Rees data or the inverted perturbation approach data, and that they are much better than other analytical potentials such as the Morse and the Huxley-Murrell-Sorbie potentials for the electronic excited states of alkali dia tomic molecules.

     

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