搜索

x
中国物理学会期刊

La掺杂SrBi4Ti4O15铁电材料性能研究

CSTR: 32037.14.aps.52.1524

Study of properties of lanthanum doped SrBi4Ti4O15 ferroelectric ceramics

CSTR: 32037.14.aps.52.1524
PDF
导出引用
  • 按x=0.00,0.10,0.25,0.50,0.75和1.00,采用固相烧结工艺,制备了不同La掺杂量的SrBi4-xLaxTi4O15的陶瓷样品. 用x射线衍射对其微结构进行了分析,并测量了铁电、介电性能.结果发现,La掺杂未改变SrBi4Ti 4O15的晶体结构.随掺杂量的增加,样品的矫顽场(Ec)下降,剩余极化(2P 

    Ceramic samples SrBi4-xLaxTi4O15 (x =0.00, 0.10, 0.25, 0.50, 0.75, 1.00), have been prepared by solid-state reaction method. T heir structure was analyzed by x-ray diffraction, and their dielectricity and fe rroelectricity were measured. It is found that La-doping does not change the cry stal structure of SrBi4Ti4O15. The remnant pola rization (2P4) in creases at first, then decreases with the increase of La content. The 2P4 reaches a maximum value of 24.2 μC·cm-2, when x is 0.25. The c oerc ive field of SrBi3.75La0.25Ti4O15 is 60.8 kV·cm-1 . The 2P4 increases by about 50% and the Ec decrease s near 25%, compa red with these of SrBi4Ti4O15. Obviously, the f erroelectricity of SrBi 4Ti4O15 is improved by lanthanum doping. The te mperature of p hase transition (Tc) decreased with La cloping. The Tc of SrBi3.75La0.25Ti4O15 is 451 ℃. When x=0.75 and 1.00, the SrBi4-xLaxTi4O15 exhibit the typical characteristics of relaxor ferro electrics.

     

    目录

    /

    返回文章
    返回