Microcrystalline phases were produced by laser irradiation on the Fe73.5Cu1Nb3Si13.5B9 amorphous ribbon with a power ranging from 40 to 170W,scaning speed 10mm/s,laser beam spot 20mm. Hyperfine structures of the original and crystallized samples were analyzed by transmission Mssbauer spectros copy. We discovered that the basic parameters of the Mssbauer spectra——isome r shift（IS）, quadrupole splitting（QS） and hyperfine magnetic field（Hhf） ch ange with the laser power. Experimental results show that the magnetic moment re organization of Fe73.5Cu1Nb3Si13.5 B9 amorphous phases has take n place and the atom magnetic moment direction maintains a preferred in-plane or ientation, The average hyperfine magnetic field of the amorphous phase is improv ed because of the microcrystalline phase. The crystallized phase was Fe-Si alloy with a DO3 structure, and the area of its spectral lines is about 2% —3.4%. This is caused by the jump of one electron in Fe atom 3d6 shell int o Si atom 3p2 shell, forming a stability electron group.