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中国物理学会期刊

双振子模型手性分子介质的二次谐波理论

CSTR: 32037.14.aps.52.372

Second harmonic theory of two coupled oscillators in chiral molecular media

CSTR: 32037.14.aps.52.372
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  • 推导了在二次谐波条件下耦合双振子模型手性分子的一阶超极化率,给出了薄膜手性介质的二阶极化率,分析了分子的微观参量对二次谐波产生效率的影响.理论计算所得的偏振旋转角谱和已有的实验结果相符.

     

    We have derived the hyperpolarizability of a chiral molecule from the model of coupled two-oscillators in second-harmonic generation. We gave the susecptibility of a thin film. We discussed the influence of microscopic parameters of a molecule on the efficiency of second-harmonic generation through the relationship of hyperpolarizabilities and susceptibilities. We also have simulated the spectrum of rotational angle of polarization state. Our theoretical results fit the known experimental facts.

     

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