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We have derived the hyperpolarizability of a chiral molecule from the model of coupled two-oscillators in second-harmonic generation. We gave the susecptibility of a thin film. We discussed the influence of microscopic parameters of a molecule on the efficiency of second-harmonic generation through the relationship of hyperpolarizabilities and susceptibilities. We also have simulated the spectrum of rotational angle of polarization state. Our theoretical results fit the known experimental facts.
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Keywords:
- chiral molecular medium /
- hyperpolarizability /
- susceptibility /
- second-harmonic generation







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