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中国物理学会期刊

掺铒重金属氧氟硅铋酸盐玻璃的光谱性质

CSTR: 32037.14.aps.53.1378

Spectroscopic properties of Er3+-doped heavy metal oxyfluoride bismuth silicate glasses

CSTR: 32037.14.aps.53.1378
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  • 研究了重金属氧氟硅铋酸盐玻璃 (50-x)SiO2xBi2O350PbF2(x=0, 3, 5, 8, 10, 13, 15 mol%)中Er3+离子的吸收光谱、荧光光谱、荧光半高宽、荧光 寿命和热稳定性能.应用JuddOfelt理论计算了玻璃的强度参数Ωt(t=2,4,6),应用 McCumber计算了能级4I13/2→4I15/2跃迁的受激发射截面. 结果发现荧光半高宽与Ω6有较大联系,Ω6越大,荧光半高宽越宽.对Er3+

     

    The absorption spectra, fluorescence spectra, fluorescence lifetime and thermal stability of Er3+doped (50x)SiO2xBi2O350PbF2 (x =0, 3, 5, 8, 10, 13, 15 mol%) glasses were investigated. The intensity paramet ers Ωt (t=2,4,6) were calculated by JuddOfelt theory, and the stimulate d emission sectionsections of 4I13/2→4I15/2 transitio ns were calculated by McCumber. The results showed that the FWHM value is relate d to the Ω6 parameter, and the larger the Ω6 parameter, the broade r the FWHM. Compared with other glass hosts, the gain bandwidth property of Er 3+doped SBP3 glass is close to those of tellurite and bismuth glasses, and much greater than those of silicate, a phosphate and germanate glass, which sho ws that Er3+doped heavy metal oxyfluoride bismuth silicate glasses can b e used as host materials for broadband optical amplifier.

     

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