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中国物理学会期刊

(Nd1-xErx)2Co15.5V1.5的结构转变与磁性

CSTR: 32037.14.aps.53.1903

Structure transition and magnetic properties of ((Nd1-xErx)2Co15.5V1.5 compounds

CSTR: 32037.14.aps.53.1903
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  • 利用电弧熔炼制备了(Nd1-xErx)2Co15.5V1.5(x=0—1.0)化合物样品.通过x射线衍射分析和磁性测量研究了Er替代Nd2Co15.5V1.5中的Nd时对化合物结构和磁性的影响.研究结果表明,低Er含量(x0.),化合物转变为Th2Ni17结构;Er含量为x=0.4和0.5时,两种结构共存.两种结构的晶胞参数a,c和晶胞体积V随着Er含量的增加都呈现递减的趋势.随着Er含量的增加,(Nd1-xErx)2Co15.5V1.5化合物的

     

    Structure and magnetic properties of (Nd1-xErx)2Co15.5V1.5compounds have been investigated by means of x-ray diffraction and magnetic measurements. The results obtained show that the (Nd1-xErx)2Co15.5V1.5 compounds crystallize in the Th2Zn17type structure for lower Er content(x0.5). The two structures coexist in the samples with x=0.4 and 0.5 The lattice constants a and c, and the unit cell volumeV show a decreasing tendency with increasing Er content in both structures. With increasing Er content, at room temperature, the anisotropy of the (Nd1-xErx)2Co15.5V1.5 compounds changes from the easycone type for low Er content(x0.5). The spin reorientation transition is observed for the compounds with x=0.0—0.5, and the spin reorientation temperature Tsr shows a decreasing tendency with increasing Er content. In addition, the Curie temperature TC and saturation magnetization Ms also decrease monotonically with the Er substitution for Nd in (Nd1-xErx)2Co15.5V1.5 compounds.

     

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