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中国物理学会期刊

La掺杂诱发层状钙钛矿型铁电体弛豫性相变的介电研究

CSTR: 32037.14.aps.53.276

Dielectric study on relaxor-like phase transition of lanthanum doped bismuth layer-structured ferroelectrics

CSTR: 32037.14.aps.53.276
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  • 制备了La掺杂层状钙钛矿铁电体材料SrBi4Ti4O15, Sr2Bi4Ti5O18以及共生结构Bi4Ti3O12-SrBi4Ti4O15,通过研究样品的变温介电特性发现,SrBi4-xLax

     

    Lanthanum doped bismuth layer-structured ferroelectrics and its intergrowth type, SrBi4-xLaxTi4O15, Sr2LaxBi4-xTi5O18, and (Bi,La)4Ti3O12-Sr(Bi,La)4Ti4O15, have been prepared by solid-state reaction method. The dielectric properties of those materials are measured. The results show that SrBi4-xLaxTi4O15 (x=1.0), Sr2LaxBi4-xTi5O18(x≥0.5), (Bi,La)4Ti3O12-Sr(Bi,La)4Ti4O15(x=1.50) exhibit typical relaxational characteristics. The degree of diffuseness and relaxation increased with increasing La3+ content. The origin of relaxation is the microdomain induced by La3+ doing. The micromechanism corresponding to the transition between normal ferroelectrics and relaxors is explained as the transition from the macrodomain of normal ferroelectrics to the microdomain of relaxors.

     

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