搜索

x
中国物理学会期刊

La2NiO4+δ体系相分离现象的低频内耗研究

CSTR: 32037.14.aps.53.3834

Phase separation in La2NiO4+δ studied by lowfrequency internal friction technique

CSTR: 32037.14.aps.53.3834
PDF
导出引用
  • La2NiO4+δ体系额外氧δ=0.071,0.110,0.135,0.140样品中存在着 一个间隙氧弛豫运动引起的低频内耗峰,其内耗峰峰位置随额外氧的增多向高温移动.而额外氧处于其间位 置δ=0.087样品中则出现了两个弛豫型内耗峰,分析认为它们源于体系相分离后形成的不同一维有序结构中间隙氧的跳跃. 此外,额外氧δ=0.038样品中也观察到两个弛豫型内耗峰,其中低温峰性质与上相同,而高温内耗峰则可能对应于体系相分离后形成的低温四方相中氧原子的跳跃弛豫.

     

    There exists a low-frequency relaxation internal friction peak in La2NiO4+δwithδ=0.071, 0.110, 0.135 and 0.140, the peak position shifting to higher temperatu re, when more excess oxygen is incorporated. At δ=0.087 two peaks were obse rved which may be attributed to the jump of the interstitial oxygen atoms in the diff erent kind of the one-dimensional ordering phase formed by phase separation. At δ=0.038 two peaks were also observed which may be attributed to the jump of the i nterstitial oxygen atoms in the low-temperature tetragonal phase and the one-dimensional ordering phase formed by phase separation.

     

    目录

    /

    返回文章
    返回