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中国物理学会期刊

新型Pr基大块非晶及其特性研究

CSTR: 32037.14.aps.53.850

A new Pr-based bulk metallic glass and its properties

CSTR: 32037.14.aps.53.850
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  • 用铜模吸铸法获得了直径为5mm的一种新的Pr基大块非晶.与以往其他稀土-过渡金属(RE-TM)大块非晶不同的是,这种新的Pr基大块非晶具有明显的玻璃转变和稳定的过冷液相区,且其玻璃转变温度在目前已知的大块非晶中是最低的,Tg=409K.研究了该大块非晶的玻璃转变动力学,并给出了Kauzmann温度Tk、Vogel-Fulcher温度T0g及脆性参数m等重要参数.

     

    A new rare-earth Pr-based bulk metallic glass (BMG) is obtained in the shape of rod up to 5 mm in diameter by die cast. Unlike other rare-earth based BMGs, it exhibits a distinct glass transition, Tg=409K,the lowest glass transition temperature among the known BMGs, a large and stable supercooled liquid region and paramagnetic property. The glass transition as well as its kinetic nature and the fragility parameters m of the BMG have been studied. The BMG offers an ideal model to investigate the nature of glass transition as well as the relaxation and nucleation with a large experimentally accessible time and temperature window at very low temperature region.

     

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