In this paper, the control of chaotic externalinjection multiplequantumwell laser synchronization via phasecontrollers is presented and external chaos phase shift keying modulation is proposed for secure communication. Chaotic laser synchronization is numerically achieved under controlling by phasecontrollers. Lasing phase shift is controlled via continuous ON/ON chaos shift keying and chaotic laser signal is transmitted by chaos phase shift keying modulation on end. Chaotic laser demodulation is realized by setting a phase shift of the receiver phasecontrollers. ON/ON chaos phase shift keying communications at bit rates of 01 and 05Gbit/s are numerically simulated. ON/ON chaos phase shift keying communication bit rate，the synchronization characterization and the system parameter mismatch are numerically analyzed, in particular.