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中国物理学会期刊

(Nd1-xErx)3Fe25Cr4.0(0≤x≤1.0) 化合物的结构与磁性

CSTR: 32037.14.aps.54.2176

Structure and magnetic properties of (Nd1-xErx)3Fe25Cr4.0 compounds

CSTR: 32037.14.aps.54.2176
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  • 合成了(Nd1-xErx)3Fe25Cr40(0≤x≤10)系列化 合物并采用x射线衍射和磁测量等手段研究了它们的结构和磁性. 发现当0≤x≤08时化合物保持Nd3(Fe,Ti)29型结构,属于单斜晶系,A2/m空间群 ,当082Ni17结构 ,P63/m mc空间群. 随着Er含量的增加,化合物的居里温度TC和饱和磁化强度Ms单调下降. 当x=0时,Nd3Fe25Cr40化合物的易磁化方 向非常靠近[040] 方向, 仅略微偏离1∶5结构的基面,但随Er含量的增加,(Nd1-xErx)3Fe25Cr40化合物的易磁化方向从靠 近[040]方向转向靠近[4 0 2]方向,同时与1 ∶5结构的基面所成的倾角也增大. 通过测量交流磁化率发现,x=0—04和x=10的化合 物在低温下出现自旋重取向. 在x=0—04的化合物中,自旋重取向温度Tsr 随Er含量增加单调升高. 用高达13T的磁场测量难磁化方向的磁化曲线发现,在0≤x≤0 8的化合物中发生了一级磁化过程(FOMP),其临界场Bcr随Er含量的增加而 降低.

     

    Structure and magnetic properties of the (Nd1-xErx)3Fe25Cr40 (x=0—10) compounds have been investigated by means of x -ray diffraction and magnetic measurements. It is found that the compounds with x =0—08 crystallize in Nd3(Fe,Ti)29-type structure, A 2/m space grou p, but those with 082Ni17-type structure, P63/mmc space group. Both the Curie tem perat ure Tc and the saturation magnetization Ms of (Nd1 -xErx)3Fe25Cr40 de crease monotonically with increasing Er content. The easy magne tization direction (EMD) of the Nd3Fe25Cr40 compound is close to the [040] direction at room temperature, but makes a tilted angle with the ba sal plane of 1∶5 structure. With increasing Er content the EMD changes to much close to the 402 direction and the tilted angle increases. AC susceptibility m easurement indicates the appearance of a spin reorientation at low temperatures for the compounds with x=0—04 and x=10, and the spin reorientation temperature Tsr increases monotonically as the Er content increas es fo r the compounds with x=0—04 First-order magnetization process (FOMP) is observed in the compounds with 0≤x≤08 and the critical field Bc rof the FOMP decreases with increasing Er content from 66T for x=0 to 20T for x=07

     

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