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中国物理学会期刊

非晶/微晶相变域硅薄膜及其太阳能电池

CSTR: 32037.14.aps.54.3327

Transition films from amporphous to microcrystalline silicon and solar cells

CSTR: 32037.14.aps.54.3327
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  • 采用甚高频等离子体增强化学气相沉积(VHF-PECVD)法,成功制备出从非晶到微晶过渡区 域的硅薄膜. 样品的微结构、光电特性及光致变化的测量结果表明这些处于相变域的硅薄膜 兼具非晶硅优良的光电性质和微晶硅的稳定性. 用这种两相结构的材料作为本征层制备了p- i-n太阳能电池,并测量了其稳定性. 结果在AM15(100mW/cm2) 的光强下曝光 800—5000min后,开路电压略有升高,转换效率仅衰退了29%.

     

    A series of hydrogenated silicon films near the threshold of crystallinity was p repared by very high frequency plasma-enhanced chemical vapor deposition (VHF-PE CVD)from a mixture of SiH4 diluted in H2. The effect of h ydrogen di lution ratios R= [H2]/[SiH4] on the microstructure o f the films was investigated. The photoelectronic properties and stability of the film s were studied as a function of crystalline fraction. The results show that t he diphasic films gain both the fine photoelectric properties like a-Si:H an d high stability like μc-Si:H. By using the diphasic silicon films as the intrinsic layer, p-i-n junction solar cells were prepared. Current-voltage (J-V) characteristics and stability of the solar cells were measured under an AM15 solar simulator. We observed a light-induced increase of 52% in the ope n-circuit voltage (Voc) and a light-induced degradation of ~29% in efficiency.

     

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