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中国物理学会期刊

YBCO熔融织构准单晶中的进氧和脱氧扩散研究

CSTR: 32037.14.aps.54.3380

The oxygen in- and out-diffusion behavior in melt-textured YBCO measured by thermogravimetry

CSTR: 32037.14.aps.54.3380
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  • 采用热重法研究了YBCO熔融织构准单晶中氧的化学扩散过程. 与以往的实验不同,采用固定 氧偏压变化温度的方法获得氧浓度梯度. 拟合实验所得重量等温弛豫曲线可知,在375—600 ℃温区内,熔融织构准单晶的氧化学扩散系数比单晶体高出约50%,但都约为10-10c m2s-1,激活能为~1eV. 对YBCO熔融织构准单晶中的进氧和脱氧研 究表 明两者具有相同的速率,证实实验过程中环境氧分压的改变会导致进氧和脱氧过程不一致.

     

    The chemical oxygen in- and out-diffusion in melt-textured YBa2Cu 3O7-δ(YBCO)is investigated by thermogravimetry. The weight relaxations resulting from the sudden change of temperature at a fixed oxygen partial pressure of 033×105Pa are recorded. By fitting the isothermal curves, the chemical diffusion coefficients at 375—600℃ are determined. It is found that the resultant numerical values for melt-textured YBCO are larger than that of crushed single crystal YBCO obtained in our previous study by about 50%, whereas all of them are of the order of 10-10cm2s-1 . The activation energies for both samples are estimated as ~1eV. It is believed that those values represent the nature of the lattice diffusion. The oxygen diffusion in me lt-textured-grown-YBCO is attributed to the YBCO matrix and the micro-cracks are responsible for the huge diffusion coefficients. Moreover, the same kinetics o f in- and out-diffusion is confirmed to be intrinsic, and it suggests that the d ifferent in- and out-diffusion coefficients measured in other works are controll ed by the large concentration gradient and the shell effect.

     

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